{"id":120,"date":"2019-07-26T15:56:20","date_gmt":"2019-07-26T19:56:20","guid":{"rendered":"https:\/\/sites.bsu.edu\/enact\/?p=120"},"modified":"2019-08-15T00:03:16","modified_gmt":"2019-08-15T04:03:16","slug":"how-nonreactive-can-a-material-really-be","status":"publish","type":"post","link":"https:\/\/sites.bsu.edu\/enact\/how-nonreactive-can-a-material-really-be\/","title":{"rendered":"How Nonreactive can a Material Really Be?"},"content":{"rendered":"<h1 style=\"text-align: center\">How Nonreactive can a Material Really Be?<\/h1>\n<h2 style=\"text-align: center\">By Tristan Maxson<\/h2>\n<p>As a scientist, we are commonly taught that some materials are chemically inactive for reactions; this is not true.\u00a0 These inert, or nonreactive, materials include things such as glassware, plastics, nitrogen, and the noble gases. Due to this being taught to us very early in our education, it is hard to think of these materials as being harmful for some types of chemistry due to the rarity of reactions occurring with these.<\/p>\n<p style=\"text-align: center\"><iframe loading=\"lazy\" src=\"https:\/\/www.youtube.com\/embed\/6ZBwluyR2Tc\" width=\"560\" height=\"315\" frameborder=\"0\" allowfullscreen=\"allowfullscreen\"><\/iframe><\/p>\n<p>Glassware is a more well-known example of an inert material being chemically active since it can be etched away by some corrosive chemicals such as hydrofluoric acid and piranha acid, both of which are dangerous to work with.\u00a0 The problem with this type of understanding is that it does not present itself with more minor problems that can occur without the glass visibly changing.\u00a0 Glass can be affected by acids and bases without being destroyed when the oxygen atoms on the surface of the glass are acidified or neutralized, potentially affecting the reaction or measurements being done in them.<\/p>\n<p><a href=\"https:\/\/www.curbellplastics.com\/Research-Solutions\/Chemical-Resistance-of-Plastics\" target=\"_blank\" rel=\"noopener noreferrer\">Plastics are sometimes known to be inert<\/a>, but many of them are not inert to common lab chemicals.\u00a0 ABS plastics are dissolved by acetone, PLA plastics are degraded by water and sunlight, and some plastics such as Nylon are not compatible with acids.\u00a0 These plastics would not be used by a lab in direct contact with a reaction, but Teflon is incredibly common to find as a coating on stir bars.\u00a0 \u00a0Recently <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.9b00294\" target=\"_blank\" rel=\"noopener noreferrer\">a group has published their findings<\/a> on how stir bars in their labs showed catalytic activity for\u00a0 organic reactions, creating unpredictable results due to a material that is universally considered to be inert in presence of almost all reactants.\u00a0 We have incorporated their findings into my own research where we have started using glass stir bars for one project.\u00a0 By switching stir bars and making a few other changes, we were able to reduce the error in our experiments from about 10% to closer to 1-2%.<\/p>\n<p><a href=\"https:\/\/www.google.com\/url?sa=i&amp;source=images&amp;cd=&amp;ved=2ahUKEwir0LSmsNPjAhWTbs0KHXSdAtYQjRx6BAgBEAU&amp;url=https%3A%2F%2Fcommons.wikimedia.org%2Fwiki%2FFile%3AXenon-hexafluoride-3D-balls-D.png&amp;psig=AOvVaw1CAgudlHPWFc0Yxw1YO5ni&amp;ust=1564257732315386\" target=\"_blank\" rel=\"noopener noreferrer\"><img loading=\"lazy\" decoding=\"async\" class=\"alignleft wp-image-123 \" src=\"https:\/\/bsu-wpe-sites.s3.amazonaws.com\/wp-content\/uploads\/sites\/22\/2019\/07\/26160144\/XeF6.jpg\" alt=\"\" width=\"136\" height=\"207\" srcset=\"https:\/\/bsu-wpe-sites.s3.amazonaws.com\/wp-content\/uploads\/sites\/22\/2019\/07\/26160144\/XeF6.jpg 322w, https:\/\/bsu-wpe-sites.s3.amazonaws.com\/wp-content\/uploads\/sites\/22\/2019\/07\/26160144\/XeF6-197x300.jpg 197w\" sizes=\"auto, (max-width: 136px) 100vw, 136px\" \/><\/a>Oxygen is well understood as a chemically active gas which can be crucial for life, combustion of materials, and for corrosion of metals.\u00a0 To remove oxygen from reactions, it is common to purge the solution with nitrogen or noble gases such as argon to displace the oxygen.\u00a0 While these gases are normally inert, it is well known that some noble gases can form molecules with fluorine such as xenon hexafluoride, but this would be unlikely to happen unintentionally.\u00a0 Nitrogen is also very inert but under high pressure or temperature conditions it can become reactive and some groups have been working to find <a href=\"https:\/\/www.nature.com\/articles\/s41557-018-0167-8\" target=\"_blank\" rel=\"noopener noreferrer\">ways to make it reactive at ambient conditions<\/a>.\u00a0 Typically its strong bond is hard to break, but that doesn\u2019t make it impossible to break when in contact with a catalyst lowering the barrier for dissociation.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-124 alignright\" src=\"https:\/\/bsu-wpe-sites.s3.amazonaws.com\/wp-content\/uploads\/sites\/22\/2019\/07\/26160648\/Stir-Bar-300x239.jpg\" alt=\"\" width=\"196\" height=\"156\" srcset=\"https:\/\/bsu-wpe-sites.s3.amazonaws.com\/wp-content\/uploads\/sites\/22\/2019\/07\/26160648\/Stir-Bar-300x239.jpg 300w, https:\/\/bsu-wpe-sites.s3.amazonaws.com\/wp-content\/uploads\/sites\/22\/2019\/07\/26160648\/Stir-Bar.jpg 379w\" sizes=\"auto, (max-width: 196px) 100vw, 196px\" \/><\/p>\n<p><a href=\"https:\/\/www.curbellplastics.com\/Research-Solutions\/Chemical-Resistance-of-Plastics\" target=\"_blank\" rel=\"noopener noreferrer\">Plastics are sometimes known to be inert<\/a>, but many of them are not inert to common lab chemicals.\u00a0 ABS plastics are dissolved by acetone, PLA plastics are degraded by water and sunlight, and some plastics such as Nylon are not compatible with acids.\u00a0 These plastics would not be used by a lab in direct contact with a reaction, but Teflon is incredibly common to find as a coating on stir bars. Recently <a href=\"https:\/\/pubs.acs.org\/doi\/10.1021\/acscatal.9b00294\" target=\"_blank\" rel=\"noopener noreferrer\">a group has published their findings<\/a> on how stir bars in their labs showed catalytic activity for\u00a0 organic reactions, creating unpredictable results due to a material that is universally considered to be inert in presence of almost all reactants.\u00a0 We have incorporated their findings into my own research where we have started using glass stir bars for one project.\u00a0 By switching stir bars and making a few other changes, we were able to reduce the error in our experiments from about 10% to closer to 1-2%.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>How Nonreactive can a Material Really Be? By Tristan Maxson As a scientist, we are commonly taught that some materials are chemically inactive for reactions; this is not true.\u00a0 These inert, or nonreactive, materials include things such as glassware, plastics, nitrogen, and the noble gases. Due to this being taught to us very early in [&hellip;]<\/p>\n","protected":false},"author":68,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[4],"tags":[],"class_list":["post-120","post","type-post","status-publish","format-standard","hentry","category-summer-2019-blogs"],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.7 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>How Nonreactive can a Material Really Be? - Early Navigation through Advanced Chemical Topics (EN+ACT)<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/sites.bsu.edu\/enact\/how-nonreactive-can-a-material-really-be\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"How Nonreactive can a Material Really Be? - Early Navigation through Advanced Chemical Topics (EN+ACT)\" \/>\n<meta property=\"og:description\" content=\"How Nonreactive can a Material Really Be? By Tristan Maxson As a scientist, we are commonly taught that some materials are chemically inactive for reactions; this is not true.\u00a0 These inert, or nonreactive, materials include things such as glassware, plastics, nitrogen, and the noble gases. 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